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The water exposure is spot on showing the movement. I would have used an ND 06 Grad on the sky or developed the sky in PS / Color efex is a good programme for landscapes. You can use the sliders to add the gradient to your own style and taste. I always set the shutter speed to 0.3 of a second for water wether it be a river or a seascape. This will give full definition of water movement.