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You've already mentioned many of the things I was going to point out. The light coming from behind her is perfect -- it keeps her face illuminated without creating harsh shadows and I love the way it lights that hair that is blowing back behind the girl.
I absolutely love this shot and that sign reminds me of one of our local pubs, The Congregation.
You say "obviously enhanced in PS." However, as vivid as as they appear, it is not crazy enough to be obvious. In other words, perfect processing.