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The composition, mood and clarity work for me.
Firstly, the composition, style, pose and authenticity of the image is good.
I like the composition, mood and detail in the image.
I would say that for a first portrait it is far better than many first attempts.
Backlighting doesn't necessarily need to be directly at the back of the model. Having 2 lights to the side will work also. The key is not to make the model sillhoutted. To avoid this experiment with a reflector (even one of those car shades with a shiny surface on one side), use the reflector to bounce light back to the models rear from the side where the camera is.
I do like the image, and the poses. I have uploaded a mod that has a few things done to it that I think will give it a little more 'punch' and realism.
I think a few of these points have been raised above but:
The pose and eye contact or spot on.
I agree totally with what Dave has said. I produced a series for an exhibition of Sadhus whilst I was in India (examples are in my portfolio).
Ian is right in what he has said. If you go for a landscape format dont be afraid to go close in with your crop; even cropping across the top of the hair - this will also lift the person higher into the frame, and therefore having more impact (at the moment she is slumped in the lower half).
Im not too sure about the shot. The title refers to the wet paint, yet the image doesn't show much of this within the shot (it is there, but is lost within the shot); possibly if the image had been in colour then it may have worked better.
Produced a quick mod to show how I would present the image.